Rotational analysis of the A2Π → X2Π system of As35Cl+

J. A. Coxon; P. G. Hajigeorgiou; P. I. Presunka

doi:10.1016/0584-8539(89)80134-5

Rotational analysis of the A2Π → X2Π system of As35Cl+

J. A. Coxon
, P. G. Hajigeorgiou
, P. I. Presunka

Medical School

Dalhousie University

Research output: Contribution to journal › Article › peer-review

Abstract

The visible A²Π → X²Π emission band system of AsCl⁺ has been recorded photoelectrically at medium resolution in the wavelength range 5210-7215 Å. Twelve ²Π_{1 2} ²Π_{1 2} sub-bands of As³⁵Cl⁺ with ν′=0,1 and 14≤ν″≤25 have been rotationally analysed. A total of 425 line positions have been employed in direct least-squares fits of the molecular parameters of the two states. The equilibrium internuclear separations are r_e(X) = 2.031 and r_e(A) = 2.498 Å.

Original language	English
Pages (from-to)	281-284
Number of pages	4
Journal	Spectrochimica Acta Part A: Molecular Spectroscopy
Volume	45
Issue number	2
DOIs	https://doi.org/10.1016/0584-8539(89)80134-5
Publication status	Published - 1989

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@article{7028aa5c07324719b95a807de2e33ce7,

title = "Rotational analysis of the A2Π → X2Π system of As35Cl+ ",

abstract = "The visible A2Π → X2Π emission band system of AsCl+ has been recorded photoelectrically at medium resolution in the wavelength range 5210-7215 {\AA}. Twelve 2Π 1 2 2Π 1 2 sub-bands of As35Cl+ with ν′=0,1 and 14≤ν″≤25 have been rotationally analysed. A total of 425 line positions have been employed in direct least-squares fits of the molecular parameters of the two states. The equilibrium internuclear separations are re(X) = 2.031 and re(A) = 2.498 {\AA}.",

author = "Coxon, \{J. A.\} and Hajigeorgiou, \{P. G.\} and Presunka, \{P. I.\}",

year = "1989",

doi = "10.1016/0584-8539(89)80134-5",

language = "English",

volume = "45",

pages = "281--284",

journal = "Spectrochimica Acta Part A: Molecular Spectroscopy",

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T1 - Rotational analysis of the A2Π → X2Π system of As35Cl+

AU - Coxon, J. A.

AU - Hajigeorgiou, P. G.

AU - Presunka, P. I.

PY - 1989

Y1 - 1989

N2 - The visible A2Π → X2Π emission band system of AsCl+ has been recorded photoelectrically at medium resolution in the wavelength range 5210-7215 Å. Twelve 2Π 1 2 2Π 1 2 sub-bands of As35Cl+ with ν′=0,1 and 14≤ν″≤25 have been rotationally analysed. A total of 425 line positions have been employed in direct least-squares fits of the molecular parameters of the two states. The equilibrium internuclear separations are re(X) = 2.031 and re(A) = 2.498 Å.

AB - The visible A2Π → X2Π emission band system of AsCl+ has been recorded photoelectrically at medium resolution in the wavelength range 5210-7215 Å. Twelve 2Π 1 2 2Π 1 2 sub-bands of As35Cl+ with ν′=0,1 and 14≤ν″≤25 have been rotationally analysed. A total of 425 line positions have been employed in direct least-squares fits of the molecular parameters of the two states. The equilibrium internuclear separations are re(X) = 2.031 and re(A) = 2.498 Å.

UR - https://www.scopus.com/pages/publications/4243485434

U2 - 10.1016/0584-8539(89)80134-5

DO - 10.1016/0584-8539(89)80134-5

M3 - Article

AN - SCOPUS:4243485434

SN - 0584-8539

VL - 45

SP - 281

EP - 284

JO - Spectrochimica Acta Part A: Molecular Spectroscopy

JF - Spectrochimica Acta Part A: Molecular Spectroscopy

IS - 2

ER -

Rotational analysis of the A2Π → X2Π system of As35Cl+

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